Before we're done with this program we will have studied the composition of atoms and the early attempts at understanding their structure. We will see how atoms can be studied by shooting atomic bullets at them and how they behave quite different from what we expect. The photoelectric effect will show us that their behavior is consistent and will lead us to the understanding of the atom as a quantitized system. The relationship between waves and particles will be extended from light to matter in general as we engage in a paradigm clash, the resolution of which allowed a deeper understanding of atoms and their properties, and the role of electrons in chemical bonding and the macroscopic properties of matter.
1. How are cathode rays produced, where do they come from, and what are their properties?
2. What significance did the discovery of the electron have for atomic theory?
3. What was the Fruit Cake model of the atom?
4. Name three types of radioactivity and list the characteristics of each.
5. What problems did the discovery of radioactivity cause for physical scientists?
6. How is the radioactivity of a substance such as uranium affected by chemical combination and heat?
7. What does it mean to say that Rutherford was the first of the "big" scientists?
8. On what evidence did Rutherford base his nuclear model for the atom?
9. In what way is the nuclear model of the atom inconsistent with electromagnetic theory?
10. Briefly describe the Photoelectric Effect and the problems it raises for the wave theory of light.
11. What is meant by a "quantum" of energy?
12. What did Millikan's oil drop experiment do?
13. How did Bohr solve the problem of the nuclear atom?
14. How is the Bohr atom different from Rutherford's nuclear atom?
15. Describe the relationship between the Bohr atom and the hydrogen spectrum.
16. Discuss the statement, "The atom is mostly empty space."
1. Describe the pieces of atoms discovered late in the nineteenth century and their properties.
2. Compare and contrast the fruit cake, nuclear, and Bohr models of the atom
3. Describe the salient features of Planck's quantum hypothesis
4. Describe the problems associated with photoelectric effect and Einstein's quantum solution
5. Describe the relationship between waves and matter at the quantum level
6. Describe the paradoxes and controversy surrounding the wave-particle duality
2.1.1. Heinrich Geissler, glassblower (1814-1879) invented high vacuum pump, evacuated a glass tube
2.1.2. Plucker (1801-1868) sealed wires into the tube, connected to a battery
184.108.40.206. discovered that electricity flowed through the tube
220.127.116.11. forerunner of fluorescent lights, TV tubes, neon lights
2.1.3. Crookes (1832-1919) used induction coil to produce cathode rays
18.104.22.168. travel in straight lines, cast shadows (see Figure 11-3, p.239)
22.214.171.124. cathode rays produced by many different material have similar properties
2.1.4. provoked many questions and much further study
126.96.36.199. waves or particles?
188.8.131.52. carry negative charge (Perrin 1895)
184.108.40.206. where do they come from?
220.127.116.11.1. supply of electrical energy produced unlimited cathode rays
18.104.22.168. how could different substances produce the same kind of rays?
2.2.1. William Thomson (1856-1940)
22.214.171.124. cathode rays deflected by magnetic and electric fields
126.96.36.199.1. confirmed negative charge
188.8.131.52. used electric and magnetic fields together to show that cathode rays are streams of particles
184.108.40.206.1. measured ratio of charge to mass (e/m)
220.127.116.11.2. rays from all types of material have same e/m
18.104.22.168.2.1. 1.76x1011 coulombs/kilogram
22.214.171.124. suggested that cathode rays are streams of particles broken off from the atom
126.96.36.199.1. atoms are not the ultimate building block of matter
188.8.131.52. called the particles electrons, building blocks of atoms
2.2.2. Robert Millikan (1868-1953) used oil drop experiment to measure charge of electrons
184.108.40.206. series of experiments between 1909 and 1916 balanced electrical and gravitational force on small charged oil drops
Millikan's Oil Drop Experiment.
The charge of the electron is measured by balancing the gravitational force of statically charged oil drops with the coulomb electrical force.
From this data the total charge on the drops can be calculated. The charge on the electron can be determined mathematically. The smallest number which is a factor of all of the individual charges is the charge on the electron. It is 1.6 x 10-19 coulombs.
220.127.116.11. found that all drops carried multiples of a certain charge
18.104.22.168.1. charge comes in packages of a minimum size
22.214.171.124.1.1. e = 1.6E-19 coulombs
126.96.36.199.2. sugar lumps in coffee analogy
188.8.131.52. combined with Thomson's e/m measurements to calculate mass of electron
184.108.40.206.1. mass of electron = 9x10-31 kg (very small)
220.127.116.11.2. about 1/1840 the mass of a hydrogen atom
18.104.22.168.3. Millikan won Noble Prize
2.3.1. Roentgen (1845-1923) discovered by accident
2.3.2. studying cathode rays in a Crookes tube covered with black paper
2.3.3. noticed glow on fluorescent material on bench when lights turned out
2.3.4. concluded it came from Crookes tube
22.214.171.124. cathode rays do not travel outside tube for long distances
126.96.36.199. no source of UV anywhere in lab
188.8.131.52. called it X-rays (unknown rays)
2.3.5. published results led to immediate medical applications
2.3.6. established source and nature of rays
184.108.40.206. originate at end of Crookes tube where cathode rays strike
220.127.116.11. not deflected by magnetic or electric field, so not charged particles
18.104.22.168. travel in straight lines, darken a photographic plate, have great penetrating power
22.214.171.124. wavelength is considerably shorter than UV light, frequency is high
126.96.36.199. can be polarized, diffracted, reflected, refracted like waves
2.4.1. Becquerel (1852-1909) was curious about fluorescence caused by X-rays
2.4.2. certain natural crystal fluoresce (glow), especially when illuminated by UV light
2.4.3. also knew that uranium ores darken photographic film when exposed to light
188.8.131.52. also have penetrating power, like X-rays
2.4.4. discovered by accident that light is not necessary
184.108.40.206. wrapped uranium salts in black paper, stored in drawer
220.127.116.11. affected film even in the dark
2.4.5. discovered other properties too
18.104.22.168. uranium salts continue to emit rays for indefinite period of time
22.214.171.124. radiate whether in crystalline form, in compounds, or in solutions
126.96.36.199. radiate in proportion to uranium content, pure uranium even more so
2.4.6. significance overshadowed by X-ray discovery
2.4.7. Marie and Pierre Curie did further studies
188.8.131.52. Thorium displayed radiation similar to uranium
184.108.40.206. uranium ore more radioactive than suggested by uranium content
220.127.116.11. isolated two new chemical elements (polonium and radium)
18.104.22.168.1. polonium 400 times more radioactive than uranium, radium a million times
22.214.171.124. showed that radioactivity is spontaneous in certain elements
126.96.36.199.1. unaffected by heat, pressure, chemical combination
188.8.131.52. opened question of source of energy: is energy conservation violated?
2.4.8. Ernest Rutherford (1871-1937) showed that radioactivity had two components
184.108.40.206. used electric and magnetic fields
220.127.116.11. called them alpha and beta
18.104.22.168.1. alpha particles are heavy, carry positive charge, stopped by thick paper, resemble helium atoms
22.214.171.124.2. beta particles are light, carry negative charge, stopped by thin piece of metal, resemble cathode rays
126.96.36.199. third component (gamma rays) discovered later, have no charge, resemble high energy X-rays
3.1.1. electrons can be knocked off in cathode ray tube
3.1.2. pieces of atoms ejected in radioactive decay
3.2.2. simplest structure is positive atom with negative electrons embedded like fruit in fruitcake
The Fruitcake Atom
The earliest model of the atom pictured it as a solid sphere of positive charge with negatively charged electrons embedded in in like raisins in a cookie.
These electrons were thought to be the source of the cathode rays, knocked out of the atom by high voltage electricity.
188.8.131.52. electrons kicked out of atom by electrical energy
184.108.40.206. does not explain atomic spectra nor chemical properties
Ernest Rutherford and Big Science
Ernest Rutherford was the first of the "big" scientists. Not that he was overweight, but rather that his experiments took on large proportions. His laboratory employed many professional scientists who designed and carried out experiments under Rutherford's direction.
This was a departure from the traditional small laboratory with one man designing, building, and conducting the experiment single-handedly or with laboratory assistants.
Rutherford's research not only revealed the structure of the atom, it also became the paradigm for research science worldwide.
4.1.1. gold is most dense substance known, so atoms should be massive and close together
4.3.1. occasionally one was scattered, only rarely reflected straight backwards
4.4.1. from ratio of deflected vs. undeflected atoms
4.4.2. the atom is mostly empty space
220.127.116.11. positively charged nucleus contains all positive charge and most of mass
18.104.22.168. negative charges in orbit around positive nucleus
4.5.1. electron in circular orbit is accelerated
22.214.171.124. should radiate energy and spiral into nucleus
126.96.36.199. short lifetime calculated (about 1 nanosecond)
5.1.1. energy exchanged between radiation and walls of box in equilibrium
5.1.2. contradiction between two different theories and observation
5.1.3. wavelength of maximum intensity depends only on temperature
188.8.131.52. shorter wavelength implies higher temperature
5.2.1. theory predicted that radiation would shift towards shorter wavelength (higher frequency)
5.2.2. eventually would become invisible
5.2.3. violates conservation of energy
5.3.1. Planck saved conservation of energy with simple assumption
5.3.2. intended as mathematical tool to mesh theory with observation
5.3.3. energy can only be exchanged in proportion to the frequency of the radiation
184.108.40.206. E = hf (h = Planck's constant, 6.63E-34 J s)
220.127.116.11. quantum = smallest amount of energy that can be exchanged
18.104.22.168.1. ascribes particle like properties to radiation
22.214.171.124. higher frequency means larger exchange quantum
126.96.36.199. fewer high energy states available, so little energy in high frequencies
5.3.4. observed spectrum is balance between
188.8.131.52. large number of low energy quanta, each with small energy
184.108.40.206. small number of high energy quanta, each with large energy
6.2.1. below a certain frequency no electrons are ejected (cutoff frequency)
6.2.2. above the cutoff frequency electrons have limited maximum energy
6.2.3. increasing intensity (amplitude) of light increases number of ejected electrons but does not affect their maximum energy
220.127.116.11. in classical wave theory energy of waves is proportional to amplitude
18.104.22.168. how can electrons absorb just the right amount of energy regardless of intensity?
22.214.171.124. how can energy be stored in wave until the right amount of energy has been absorbed?
6.3.1. related to Planck's quantum.
126.96.36.199. energy of light is proportional to frequency
188.8.131.52. each material has a given energy barrier to overcome (work function)
184.108.40.206.1. light with less energy than work function cannot eject electrons
220.127.116.11.2. light with more energy than work function ejects electrons
18.104.22.168.3. Emax = hf - work function
6.3.2. light exchanges energy only in bundles proportional to its frequency
6.3.3. generalized Planck's quantum to all types of EM radiation
22.214.171.124. light has wave properties in transmission, particle properties in energy exchange
7.1.1. assumed that there must be a new principle at work, since we observe that atoms are mostly stable
7.1.2. supposed that the momentum of the electron in the atom is quantitized along with its energy
126.96.36.199. orbits are stable only for certain values of momentum
188.8.131.52. used Planck's constant as quantum of momentum
7.1.3. did simple calculations to determine the radius of the hydrogen atom
184.108.40.206. results agreed with measured size of hydrogen atom
7.1.4. did simple calculation to determine the energies of the allowed quantum states
220.127.116.11. showed that difference in energy levels corresponds to wavelengths of hydrogen spectrum
18.104.22.168.1. derived Rydberg formula
7.2.1. absorption corresponds to removing light of a specific energy (wavelength) from incident spectrum
7.2.2. emission corresponds to electron losing energy to fall to a lower quantum state
8.1.1. part of Ph.D. thesis, awarded Nobel Prize
8.2.1. calculated "wavelength" of beam of electrons
8.2.2. found that electron in atomic orbit is in resonance
22.214.171.124. only orbits for which the circumference is a multiple of the wavelength are allowed
126.96.36.199.1. consistent with Bohr's atom
8.3.1. calculated wavelength matched DeBroglie's predictions
8.3.2. basis for electron microscopes
188.8.131.52. beams of electrons are focused through magnetic lenses to form magnified images
184.108.40.206.1. similar to light microscope
220.127.116.11.2. requires TV screen to see images
18.104.22.168. electrons have smaller wavelength than light for a given energy
22.214.171.124.1. smaller wavelength allows smaller objects to be seen
In this lesson we have learned how the structure of the atom was discovered. First there were pieces of atoms; the electron and radioactive particles which possessed electric charges and distinct charge to mass ratios.
Planck's quantum and the photoelectric effect indicate that radiant energy in the form of light is quantitized into packets or bundles, the size of which depends on the frequency or color of the radiation.
Bohr's suggestion that the momentum of electrons in the atom is also quantitized led him to a model of the atom which explains the Balmer spectrum using the concept of the quantum of radiant energy.
The explanation for the quantum nature of electrons in the atom came with De Broglie's discovery of the wave nature of matter which. This explained the quantitized momentum of Bohr's atom in general terms. This wave nature of matter was confirmed when a beam of electrons was observed to display diffraction similar to light waves.
This duality of waves and particles created a serious problem for physics as a science. Many years of speculation, debate and research, both experimental and theoretical followed in a very exciting period, the most productive in the history of science.